The Light Reactions Convert Solar Energy to the Chemical Energy of ATP and NADPH

Rucete ✏ Campbell Biology In a Nutshell

Unit 2 THE CELL — Concept 10.3 The Light Reactions Convert Solar Energy to the Chemical Energy of ATP and NADPH

The light reactions of photosynthesis transform solar energy into chemical energy in the form of ATP and NADPH, which power the Calvin cycle.


Light as Energy

  • Light is electromagnetic radiation, traveling in waves

  • Photons are light particles; shorter wavelengths = higher energy

  • Visible light (380–740 nm) drives photosynthesis

Photosynthetic Pigments

  • Pigments absorb specific wavelengths of light

  • Chlorophyll a is the main pigment; chlorophyll b and carotenoids are accessory pigments

  • Violet-blue and red light are most effective; green is least absorbed

  • Carotenoids also protect from excess light damage (photoprotection)

Absorption and Action Spectra

  • Absorption spectrum: shows how much light a pigment absorbs at each wavelength

  • Action spectrum: shows photosynthetic activity at each wavelength

  • Engelmann’s classic experiment confirmed that red and violet-blue light drive photosynthesis most effectively

Excitation of Chlorophyll

  • Absorption of light excites electrons to a higher energy state

  • In isolated pigments, energy is lost as heat or fluorescence

  • In chloroplasts, excited electrons are captured by a primary electron acceptor, enabling redox reactions

Photosystems and Linear Electron Flow

  • Photosystems are complexes of proteins and pigments in thylakoid membranes

  • Two types: Photosystem II (P680) and Photosystem I (P700)

  • Linear electron flow:

    • Water is split → electrons passed through PS II → PS I

    • ATP produced via chemiosmosis; NADP⁺ reduced to NADPH

    • O₂ is released as a by-product

Cyclic Electron Flow

  • Uses only Photosystem I

  • Electrons cycle back to the cytochrome complex

  • Produces ATP but no NADPH or O₂

  • May help balance ATP/NADPH needs or protect under intense light

Chemiosmosis and ATP Production

  • Electron transport chain pumps H⁺ into thylakoid space

  • H⁺ diffuses back into stroma through ATP synthase → ATP is produced

  • Chloroplast chemiosmosis is similar to that in mitochondria but powered by light rather than food-derived electrons

  • ATP and NADPH are released into the stroma to fuel the Calvin cycle

In a Nutshell

The light reactions use solar energy to split water, release O₂, produce ATP via chemiosmosis, and reduce NADP⁺ to NADPH. These energy carriers are essential for the sugar-making Calvin cycle that follows.

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